|
|
geranyl_diphosphate + esculetin <=> diphosphate + 8-geranylesculetin
|
2.5.1.138
coumarin 8-geranyltransferase
|
–
|
|
| |
BRENDA:
BR51972
KEGG:
R11603
MetaCyc:
RXN-18496
|
|
|
|
esculin + H2O <=> esculetin + D-glucose
|
2.4.1
3.2.1.182
4-hydroxy-7-methoxy-3-oxo-3,4-dihydro-2H-1,4-benzoxazin-2-yl glucoside beta-D-glucosidase
3.2.1.21
beta-glucosidase
3.2.1.78
mannan endo-1,4-beta-mannosidase
|
–
–
–
–
|
M
|
| |
BRENDA:
BS214486;
BS446940
MetaCyc:
RXN-13470
SABIO-RK:
14395
|
|
|
|
UDP-glucose + esculetin <=> cichoriin + UDP + H+
|
2.4.1.104
o-dihydroxycoumarin 7-O-glucosyltransferase
2.4.1.170
isoflavone 7-O-glucosyltransferase
2.4.1.237
flavonol 7-O-beta-glucosyltransferase
|
–
–
–
|
M
|
| |
BRENDA:
BS321949
MetaCyc:
RXN-13466
|
|
|
|
UDP-glucose + esculetin <=> esculin + UDP + H+
|
2.4.1
2.4.1.237
flavonol 7-O-beta-glucosyltransferase
|
–
–
|
M
|
| |
BRENDA:
BS390005
MetaCyc:
RXN-14182
|
|
|
|
S-adenosyl-L-methionine + esculetin <=> scopoletin + S-adenosyl-L-homocysteine + H+
|
2.1.1
2.1.1.104
caffeoyl-CoA O-methyltransferase
2.1.1.6
catechol O-methyltransferase
|
–
–
–
|
M
|
| |
BRENDA:
BS420244
MetaCyc:
RXN-13473
|
|
|
|
cichoriin + H2O <=> esculetin + D-glucose
|
3.2.1
|
–
|
M
|
| |
MetaCyc:
RXN-13464
|
|
|
|
UDP-glucose + esculetin <=> 4-O-beta-D-glucosyl-esculetin + UDP + H+
|
2.4.1.126
hydroxycinnamate 4-beta-glucosyltransferase
|
–
|
M
|
| |
MetaCyc:
RXN-13471
|
|
|
|
UDP-glucose + esculetin <=> 3-O-beta-D-glucosyl-esculetin + UDP + H+
|
2.4.1
|
–
|
M
|
| |
MetaCyc:
RXN-13472
|
|
|
|
S-adenosyl-L-methionine + esculetin <=> 6-hydroxy-7-methoxycoumarin + S-adenosyl-L-homocysteine + H+
|
2.1.1
|
–
|
M
|
| |
MetaCyc:
RXN-13474
|
|
|
|
umbelliferone <=> esculetin
|
not assigned
|
–
|
M
|
| |
MetaCyc:
RXN-14165
|
|
|
|
6'-hydroxycaffeoyl-CoA <=> esculetin + CoA
|
not assigned
|
–
|
M
|
| |
MetaCyc:
RXN-16763
|
|
|
|
esculetin + O2 <=> 2H-chromene-2,6,7-trione + H2O
|
1.14.18.1
tyrosinase
|
–
|
|
| |
BRENDA:
BS397123
|
|
